基于一种新的均匀化实施方法的FRP刚度预测

基于一种新的渐近均匀化(AH)实施方法,预测并讨论了单向纤维增强复合材料(FRP)的宏观等效弹性性能及纤维排列方式对等效力学性能的影响。该方法方便地将有限元分析(FEA)软件作为一个工具箱使用,只需在单胞上施加简单位移周期边界条件开展静力学分析,即可经过简单计算得到等效弹性常数,相比传统均匀化实施方法显著降低了实施难度并简化了计算过程。通过对比不同数值方法的结果验证了该方法的有效性和精确性。数值结果表明:六边形排列下单向纤维增强复合材料呈现横观各向同性,而正方形排列下则呈现宏观正交各向异性,经过刚度平均化过程可得到横观各向异性材料性质,纤维体积含量对两种排列方式下材料等效弹性模量影响显著但有所差别。     

大曲率复合材料结构的缺陷特征与超声检测

采用超声回波法对大曲率碳纤维增强树脂基复合材料零件进行超声A 扫描，并对缺陷进行定位。结合缺陷区域和非缺陷区域的细观形貌金相图、宏观表面状态以及厚度测量结果的对比分析，讨论了缺陷形态与其回波波形特征的对应关系，以及缺陷可能的形成原因。结果表明，缺陷在细观尺度上呈现多处分层、气孔和孔隙密集缺陷，在宏观尺度上表现为零件表面贫胶与厚度增厚。缺陷的性质与超声A扫描的检测结果相吻合，缺陷的位置集中在零件大曲率部位，其形成原因与复合材料制造工艺密切相关。     

A novel surrogate modeling strategy of the mechanical properties of 3D braided composites

In this paper, a surrogate-based modeling methodology is developed and presented to predict the elastic properties of three dimensional (3D) four-directional braided composites. Using this approach, the prediction process becomes feasible with only a limited number of training points. The surrogate models constructed using Finite Element (FE) method and Diffuse Approximation, reduce the computational time and cost for preparing experimental samples. In the FE model, multiscale method is applied to couple the computations of elastic properties at microscale and mesoscale. Subsequently, a parametric study is performed to analyze the effects of the three design parameters on the elastic properties. Satisfactory results are obtained via the surrogate-based modeling predictions, which are compared with the experimental measurements. Moreover, the predictions obtained from surrogate models concur well with the FE predictions. This study orients a new direction for predicting the mechanical properties based on surrogate models which can effectively reduce the sample preparation cost and computational efforts.     

国产T700级碳纤维增强双马树脂基复合材料的力学性能

采用扫描电子显微镜(SEM)、反气相色谱(IGC)和X射线光电子能谱仪(XPS)对国产T700级碳纤维和东丽T700S碳纤维的表面形貌、表面能和表面化学特性进行表征,测试两种碳纤维增强双马树脂基复合材料的力学性能,考察国产碳纤维复合材料的界面黏结性能、韧性和湿热性能。结果表明:碳纤维表面特性(表面形貌、表面能和表面化学组成等)对复合材料界面黏结性能具有显著影响;国产T700级碳纤维/QY9611复合材料在室温下的界面黏结性能优于T700S/QY9611复合材料;国产T700级碳纤维/QY9611复合材料的韧性优异,冲击后压缩强度达到了国外先进复合材料IM7/5250-4的水平;经湿热处理后的层间剪切强度仍与T700S/QY9611复合材料相当,说明国产T700级碳纤维/QY9611复合材料具备良好的湿热性能。     

抗辐射保偏光纤的制备及其特性研究

通过对保偏光纤进行光漂白与低温相结合处理的方式，来提高光纤的抗辐射性能。保偏光纤再经过1.0 kGy的高剂量预辐照处理后，其损耗会明显增大。随后采用980nm的激光对光纤进行光漂白处理,其损耗并没有发生明显变化。但是，处理后的样品在小剂量辐照条件下其光纤传输呈现先减小后增大的趋势。对于通过液氮进行冷处理的预辐照样品，其光纤传输损耗得到明显的降低，同时光纤经过小剂量辐照后的损耗同样也具有先减小后增大的现象。最后，将两种处理方式相结合，一方面可以有效地降低预辐照光纤的传输损耗，另一方面也使得保偏光纤在小剂量辐照的条件下，使其传输损耗具有减小的趋势，大大提高了保偏光纤在小剂量辐照条件下的抗辐照特性。     

Influence of TiB2 particles on machinability and machining parameter optimization of TiB2/Al MMCs

In situ formed TiB₂ particle reinforced aluminum matrix composites (TiB₂/Al MMCs) have some extraordinary properties which make them be a promising material for high performance aero-engine blade. Due to the influence of TiB₂ particles, the machinability is still a problem which restricts the application of TiB₂/Al MMCs. In order to meet the industrial requirements, the influence of TiB₂ particles on the machinability of TiB₂/Al MMCs was investigated experimentally. Moreover, the optimal machining conditions for this kind of MMCs were investigated in this study. The major conclusions are: (1) the machining force of TiB₂/Al MMCs is bigger than that of non-reinforced alloy and mainly controlled by feed rate; (2) the residual stress of TiB₂/Al MMCs is compressive while that of non-reinforced alloy is nearly neutral; (3) the surface roughness of TiB₂/Al MMCs is smaller than that of non-reinforced alloy under the same cutting speed, but reverse result was observed when the feed rate increased; (4) a multi-objective optimization model for surface roughness and material removal rate (MRR) was established, and a set of optimal parameter combinations of the machining was obtained. The results show a great difference from SiC particle reinforced MMCs and provide a useful guide for a better control of machining process of this material.     

纤维增韧陶瓷基复合材料的比例极限应力与残余热应力关系

从细观力学角度分析并建立了纤维增韧陶瓷基复合材料从制备温度冷却到室温过程中产生的残余热应力与复合材料的比例极限应力的关系模型。该模型表明,减少复合材料的残余热应力或提高复合材料的纤维与基体的模量比,均可提高复合材料的比例极限应力。通过单调拉伸实验测试了先驱体浸渍裂解法(PIP)制备的2D SiC/SiC复合材料的比例极限应力,并采用文中建立的比例极限应力与残余热应力关系模型,计算出复合材料SiC基体的残余热应力为-19.5 MPa。分析表明,该结果是合理的。此外,引用了公开文献报道的5种复合材料体系数据,用于验证文中所建立的比例极限应力与残余热应力关系模型的适应性和可靠性,计算结果与实验结果最大误差为18.6%,表明该模型具有较好的适应性和可靠性,可为纤维增韧陶瓷基复合材料的研究提供新思路。     

液体天然橡胶对湿法混炼制备天然橡胶/白炭黑复合材料性能的影响

采用湿法混炼工艺制备天然橡胶/白炭黑(W(NR/SiO_2))复合材料,并采用液体天然橡胶(LNR)为增容剂,探讨了LNR对复合材料硫化特性、橡胶加工性能、白炭黑分散性、静态力学性能及动态性能的影响。结果表明:LNR具有较好的增容效果;使用LNR增容后,胶料的正硫化时间缩短,在白炭黑为70 phr时T_(90)缩短4.16 min,加工性能改善;白炭黑在NR中的分散性提高;胶料力学性能得到改善,在白炭黑为60 phr时最明显,拉伸强度和撕裂强度分别提高25.73%和66.59%;LNR增容后胶料的抗湿滑性提高且滚动阻力降低。复合材料良好的相容性是LNR与NR和白炭黑两相同时发生作用形成增容界面的结果。     

基体合金相组成对硼化物增强镁锂基复合材料组织和性能的影响

采用原位合成法制备了硼化物增强Mg-Li基复合材料。针对基体为Mg-14Li-1Al-1Y的复合材料力学性能仍不能满足工业应用需求的缺陷,以Mg-9Li-1Al-1Y镁锂合金为基体制备了硼化物增强镁锂基复合材料(其成分为(Mg-9Li-1Al-1Y)-6B_4C)。研究了Li含量对基体合金和复合材料组织和性能的影响。试验结果表明:合金Mg-9Li-1Al-1Y与合金Mg-14Li-1Al-1Y相比,其双相区组织晶粒更加细小,各力学性能均有所提高。(Mg-9Li-1Al-1Y)-6B_4C复合材料与Mg-9Li-1Al-1Y合金相比,硬度提高了66%,抗拉强度提高了31.33%,伸长率降低了15.5%。(Mg-9Li-1Al-1Y)-6B_4C与(Mg-14Li-1Al-1Y)-6B_4C相比,屈服强度降低了15.4%,硬度提高了29.3%,抗拉强度和伸长率基本保持不变。以上试验结果表明:随着Li含量的降低复合材料的力学性能没有得到提高,没有实现基体合金强度增加从而相应复合材料强度增加的试验预期,说明相比镁锂基复合材料强化机制中第二相强化与细晶强化的作用,基体强化作用较弱难以体现。     

固体冲压发动机喷管用C/C-SiC复合材料

采用"化学气相渗透+先驱体浸渍裂解"(CVI+PIP)混合工艺制备固体冲压发动机用C/C-SiC复合材料喷管内层,综合考查复合材料的微观结构、弯曲性能和抗烧蚀性能以及固冲发动机C/C-SiC喷管内层水压和点火实验。结果表明:复合材料的弯曲强度达到197 MPa,且断裂破坏行为呈现典型的韧性模式;复合材料具有优异的抗氧化烧蚀性能,氧化烧蚀200 s后线烧蚀率仅为0.0063 mm·s-1;研制的C/C-SiC复合材料构件的水压爆破压强为6.5 MPa,表明构件具有良好的整体承载能力;C/C-SiC复合材料喷管内层高温综合性能通过了固体冲压发动机点火实验考核。